Dielectric dependence of field-induced interspherical force

Running title: Force field dependence of riboswitch dynamics Force field dependence of riboswitch dynamics

Electric-field dependence of the effective dielectric constant in graphene.

The dielectric constant of a material is one of the fundamental features used to characterize its electrostatic properties such as capacitance, charge screening, and energy storage capability. Graphene is a material with unique behavior due to its gapless electronic structure and linear dispersion near the Fermi level, which can lead to a tunable band gap in bilayer and trilayer graphene, a sup...

Solvent dependence of the N-methylacetamide structure and force field.

The N-methylacetamide molecule (NMA) is an important model for peptide and protein vibrational spectroscopy as it contains the main amide chromophore. In the past, some observed NMA geometry and spectral features could not be entirely explained at the harmonic level or by a single-conformer model. In particular, the spectra were found to be very dependent on molecular environment. In this work ...

Electric-field-induced ion evaporation from dielectric liquid.

A direct proof of ion field evaporation from dielectric liquids is presented. The flux of sodium ions ejected from the surface of an electrospray of formamide is measured using time-of-flight and retarding potential techniques. The electric field at the emitting surface is varied through the electrospraying parameters. We find that the evaporated ion current is a very steep function of the elec...

Iterative Force-Field Calculation and Molecular Dynamics of Cyclooctanone

Body's iterative force-field computer program has been used to calculate strain energies in cyclooctanone (I). 348 MHZ 1H NMR spectra of (I) have been investigated over the temperature range of 25° to -160°C. Two conformation processes affect the 1H NMR spectrum of (I). Iterative force-field calculations on the conformations and conformational interconversion paths of ...